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Q.

Nitrobenzene (C6H5NO2) can be reduced to aniline (C6H5NH2) by electrolytic reduction;  the equivalent mass of nitrobenzene will be equal to (molecular  massn). The value of n is____

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answer is 6.

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Detailed Solution

C6H5NO2+6H++6e−→  C6H5NH2+2H2

The N is reduced as N3−.

Change of oxidation number is = 6 

Equivalent mass = molecular  mass6⇒n=6

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