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Nitrobenzene on reaction with conc. ${HNO}_{3} /$ $H_{2} {SO}_{4}$ at $80 - 100 ° C$ forms which one of the following products?

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1,4-Dinitrobenzene

1,2, 4-Trinitrobenzene

1,2-Dinitrobenzene

1,3-Dinitrobenzene

answer is D.

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Detailed Solution

When ${HNO}_{3}$ reacts with $H_{2} {SO}_{4}$ gives nitronium ion as a product. When the nitronium ion reacts with meta position of nitrobenzene, it gives 1,3-dinitrobenzene.

Nitration of nitrobenzene at ${125^0}C$ with mixed acids gives:A.meta -dinitrobenzeneB.ortho-dinitrobenzeneC.para-dinitrobenzeneD.$1,3,5 - $trinitrobenzene

Therefore, option D is correct.

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