Q.

Nitrogen gas is adsorbed on charcoal to the extent of  0.387cm3/g at a pressure of 1.6 atm and at temperature of 200 K, but at 250 K the same amount of adsorption was achieved only when the pressure was increased to 32 atm. The magnitude of molar enthalpy of adsorption (in kcal/mol) of nitrogen on charcoal is_________ 

(ln20=3.0,R=2  calmol1K1)

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answer is 6.

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Detailed Solution

lnP1P2=ΔHadsR(1T11T2)  or,  ln1.632=ΔHadsR(12001250)ΔHads=6000cal/mol

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