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Q.

NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation 2 N2O54NO2+O2 The initial concentration of N2O5 is lit-1 after 30 minutes. The rate of formation of NO2 is

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a

1.667×10-2 molelit -1 min-1

b

4.167×10-3 molelit -1 min-1

c

2.083×10-3 mole lit -1 min-1

d

8.33×10-3 mole lit -1 min-1

answer is A.

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Detailed Solution

2 N2O54NO2+O2

ΔN2O5=N2O5final -N2O5initial 

=2.75-3.00

=-0.25ΔN2O5dt=-0.2530=

ΔNO2dt=-42×d N2O5dt

=42×0.2530

=1.667×10-2 molelit-1 min-1

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