${\mathrm{NO}}_2$ is involved in the formation of smog and acid rain. A reaction that is important in the formation of $N{O}_2$ is ${\mathrm{O}}_9\left(\mathrm{g}\right)+\mathrm{NO}\left(\mathrm{g}\right)\rightleftharpoons {\mathrm{O}}_2\left(\mathrm{g}\right)+{\mathrm{NO}}_2\left(\mathrm{g}\right); {\mathrm{K}}_{\mathrm{c}}=6\times {10}^{94}$ , if the air over KOTA contained $1\times {10}^{-6} M{O}_3$, $1\times {10}^{-5} MN{O}_2. 5\times {10}^{-4} MN{O}_2$ and $8.2\times {10}^{-3}{\mathrm{MO}}_2$ , what can we conclude?