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Q.

Non-reactivity of aryl halides towards nucleophilic substitution due to all the following except

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a

C-Cl bond has decreased bond energy in aryl halides

b

C - Cl bond acquires double bond character

c

Phenyl carbocation cannot stabilize through resonance 

d

Difficult to replace -Cl group from more electro negative sp2 carbon

answer is A.

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Detailed Solution

A) 

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Question Image

Resonance stabilization leading to C-Cl bond acquiring double bond character

B) C-Cl bond length is 169 pm which is much lesser C-Cl single bond (177 pm) 

C) Difficult to replace -Cl group attached to more electronegative sp2 carbon

D) 

Question Image

Phenyl carbocation cannot stabilize through resonance 

E) Phenyl group is electron rich and repels the incoming necleophile 

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Non-reactivity of aryl halides towards nucleophilic substitution due to all the following except