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Q.

Number of chloride satisfying secondary valency in CoCl3.4NH3

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a

2

b

3

c

6

d

1

answer is B.

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Detailed Solution

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Primary valency corresponds to the oxidation state of central meta ion whereas secondary valency corresponds to the number of ligands directly attached to central metal ion.
Co has six coordination number. As NH3 is a neutral ligand, thereby it cannot act as primary valency.
Formula of the complex is Co(NH3)4Cl2Cl, which shows that there are 2 Cl act as secondary valency and one Cl is primary valency.

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