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Q.

Number of Correct statement(s) regarding the following first-order reaction is/are 

2N2O5g4NO2g+O2g

A) The concentration of the reactant decreases exponentially with time

B) The half life of the reaction decreases with increasing temperature 

C) The half life of the reaction depends on the initial concentration of the reactant.

D) The reaction proceeds to 99.6% completion in eight half life cycles.

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a

3

b

2

c

1

d

All

answer is A.

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Detailed Solution

According to first – order reaction, dN2O5/dt=kN2O5 . The half life can be found as t=2.303klogaax 

where, a = 100 and ax=10099.6=0.4

Then half-life period for first-order reaction is t12=In2k=0.693k.  With temperature, k increases (according to Arrhenius equation) and hence, t1/2 decreases. ( t1/2 is indirectly proportional to k),If the reaction completes to 99.6% completion then,

t99.6=2.303klog1000.4=2.303k2.4=8×0.693k=8t1/2

 

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