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Q.

Number of faradays required to prepare one mole of ethane by the electrolysis of aqueous sodium acetate is

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a

1F

b

2F

c

4F

d

0.5F

answer is B.

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Detailed Solution

2CH3COONa+2H2O2FCH3CH3+2CO2           anode+2NaOH+H2cathode; Anode: 2CH3-COO-2CH3-COO+2e 2CH3-COO2CH3+2CO2 CH3+CH3CH3-CH3 Cathode: 2H2O+2eH2+2OH- 

The left over solution becomes richer in NaOH.  pH progressively increases.

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Number of faradays required to prepare one mole of ethane by the electrolysis of aqueous sodium acetate is