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Q.

Number of lone pairs around ph6spborus in PCI5 , PCl4+ and PCl-6 are respectively:

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a

1, 2, 3

b

0, 1, 2

c

0, 0, 0

d

0, 2, 1

answer is B.

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Detailed Solution

All five of the valence electrons on the P atom—PCl5—are involved in bonding.

PCl4+:+With a plus sign, one electron has been lost; the remaining four have been bonded.

PCl-6: - Gain of 1 electron, all 6 involved in bonding, is indicated by the minus sign.

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