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Q.

Number of lone pairs of electrons in the central atom of SCl2, O3, ClF3 and  SF6, respectively are

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a

2,1,2 and 0

b

2,1,0 and 2

c

1,2,2 and 0

d

0,1,2 and 2

answer is B.

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Detailed Solution

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Step-by-Step Solution

1. SCl2

Central atom: S (Sulfur) 
Valence electrons on S = 6 
Chemical Valency: 2 (forms 2 single bonds with Cl atoms) 
Electrons used in bonding = 2 × 2 = 4 
Remaining electrons = 6 − 2 = 4 → 2 lone pairs

2. O3 (Ozone)

Central atom: O (Oxygen) 
Valence electrons on O = 6 
Chemical Valency: 2 (forms one single and one double bond) 
Electrons used in bonding = 3 pairs 
Remaining electrons = 6 − 3 = 3 pairs (1 lone pair + shared in resonance) → 1 lone pair

3. ClF3

Central atom: Cl (Chlorine) 
Valence electrons on Cl = 7 
Chemical Valency: 3 (forms 3 single bonds with F) 
Electrons used in bonding = 3 pairs 
Remaining electrons = 7 − 3 = 4 → 2 lone pairs

4. SF6

Central atom: S (Sulfur) 
Valence electrons on S = 6 
Chemical Valency: 6 (forms 6 single bonds with F) 
Electrons used in bonding = 6 pairs 
Remaining electrons = 6 − 6 = 0 → 0 lone pairs

Final Answer

Number of lone pairs on the central atom in 
SCl2, O3, ClF3, SF6 are: 
2, 1, 2, 0 respectively.

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