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Q.

Number of metals – metal bonds in Co2CO8 is ‘ x. Number of bridged carbonyl groups in Mn2CO10 is ‘ y’. x and y are respectively.

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a

0, 0

b

1, 0

c

1, 1

d

0, 1

answer is D.

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Detailed Solution

Explanation

To determine the values of x (the number of metal-metal bonds in Co2CO8) and y (the number of bridged carbonyl groups in Mn2CO10), we need to analyze the structures of these compounds.

Analysis of Co2CO8

  • Structure:
    • Dicobalt Octacarbonyl (Co2CO8) consists of two cobalt atoms bonded to eight carbon monoxide (CO) ligands.
    • In this structure, there are No metal-metal bonds, because the cobalt atoms are coordinated only through the carbonyl ligands.

Therefore, for Co2CO8:

  • Number of Metal-Metal Bonds (x): 0

Analysis of Mn2CO10

  • Structure:
    • Dimanganese Decacarbonyl (Mn2CO10) consists of two manganese atoms bonded to ten carbon monoxide (CO) ligands.
    • In this compound, there is typically 1 bridging carbonyl group, which connects the two manganese atoms.

Therefore, for Mn2CO10:

  • Number of Bridged Carbonyl Groups (y): 1

Final Answer

The combined results are:

  • x = 0
  • y = 1

The correct answer is: d. 0, 1

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Number of metals – metal bonds in Co2CO8 is ‘ x. Number of bridged carbonyl groups in Mn2CO10 is ‘ y’. x and y are respectively.