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Q.

Number of moles MnO4 required to oxidize one mole of ferrous oxalate completely in acidic medium will be

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a

7.5 moles

b

0.2 moles

c

0.6 moles

d

0.4 moles

answer is C.

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Detailed Solution

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In acidic medium MnO4- oxidizes Ferrous oxalate as follows:

2MnO4-+5C2O4-2+16H+2Mn2++10CO2+8H2O

5 moles of oxalate ions are oxidized by 2 moles of MnO4-

1 mole of oxalate ion is oxidized by ---------------?

25moles of MnO4-  

= 0.4 moles

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