Q.

Number of moles of MnO4-  required to oxidize one mole of ferrous oxalate completely in acidic medium will be

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a

0.4 moles

b

7.5 moles

c

0.2  moles

d

0.6 moles

answer is C.

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Detailed Solution

In acidic medium MnO4- oxidises ferrous oxalate as follows :
2MnO4-+5C2O4-2+16H+2Mn2++10CO2+8H2O
 5 moles of oxalate ions are oxidised by 2 moles of MnO4-.
 1 mole of oxalate ion is oxidised by
=25mole ofMnO4-=0.4moles

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Number of moles of MnO4-  required to oxidize one mole of ferrous oxalate completely in acidic medium will be