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Q.

O – O bond length in H2O2 is X than the O – O bond length in F2O2.The O – H bond length in H2O2 is Y than that of the O – F bond in F2O2.
Choose the correct option for X and Y from those given below

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a

X – longer, Y – shorter

b

X – shorter, Y – shorter

c

X – Shorter, Y – longer

d

X – longer, Y – longer

answer is A.

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Detailed Solution

Question Image

In O2F2, due to high electronegativity, the electron density is attracted by fluorine towards itself. This results in reduced O – O bond length. But in H2O2, oxygen is more electronegative than hydrogen. So, more electron density on oxygen atoms result in increased O – O bond length.

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