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Q.

Observe the following two reactions: 

SiH3Cl+(SiH3)2NHyield100%XNH3Y+NH4Cl

Question Image

 

 

 

 

 

 

 

 

Select the correct statement(s)

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a

‘P’ has pyramidal geometry around nitrogen atom

b

All atoms of molecule Y can be on the same plane

c

‘P’ is more basic than Y

d

Z contains   Question Image   linkage

answer is A, C.

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Detailed Solution

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X=(SiH3)3NH+ClY=(SiH3)3N P=(CH3)3NQ=qNH4Cl

Lone pain on ‘N’ in Y is involved in back bonding hence it is less basic then P.
 Y is planar about ‘N’ but tetrahedral about silicon.
(CH3)3N+CH3COOH(CH3)3NH+CH3COO¯   salt (acid-base reaction) 

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