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Q.

Observe the statements.
1) Dipole-Dipole interaction energy between rotating polar molecules is proportional to 1r6[r = distance between polar molecules]
2) London forces are always attractive and interaction energy is inversely proportional to 1r6 [r = distance between two particles]
3) Dipole-Dipole interaction energy between stationary polar molecules is proportional to 1r3
4) The order of thermal energy is “solid < liquid < gas”.
The correct statements are

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a

2, 3, 4 only

b

1, 2, 3 only

c

1, 2, 3, 4

d

1, 3, 4 only

answer is D.

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Detailed Solution

Dipole dipole interaction energy between stationary polar molecules is proportional to 1/r3 and that between the rotating polar molecules is proportional to 1/r6 where r is the distance between the molecules .

London dispersion forces are always attractive and operate only over very short distance. The energy of interaction varies as 1distance between two interacting particles6

Solid < liquid < gas. This is because solid absorb energy to change into a liquid which further absorbs energy to change into a gas.

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