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Q.

Obtain an expression for the work done by an ideal gas during adiabatic change and explain.

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Detailed Solution

Consider certain amount of gas of volume V1 at a pressure P1. The temperature of the gas is T1. Let the gas expand adiabatically to the volume V2. The pressure and temperature change to P2 and T2.
The workdone during a small change in volume at a pressure P, dW = Pdv
The total workdone during the change in volume from V1 to V2 is given as
W=dW=V1V2Pdv
but pvγ=const(k); p=kvγ

Question Image

w=V1V2kvγdv=V1V2kvγdv=kvγ+1γ+1V1V2=k1γV2γ+1V1γ+1=11γkV2γ+1kV1γ+1=11γp2V2γV2γ+1p1V1γV1γ+1=11γp2V2p1V1
but p1V1=RT1 and p2V2=RT2
w=11γRT2RT1;w=R1γT2T1

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