Questions

Octahedral molecule among the following is

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{SO}_{3}

{CHCl}_{3}

{SF}_{6}

{PCl}_{5}

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detailed solution

Correct option is C

$S : 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{4} Excited state : 1 s^{2} 2 s^{2} 2 p^{6} [3 s^{1} 3 p^{3} 3 d^{2}]$

Here one 3s, three 3p, and two 3d orbitals undergo hybridization forming the formation of six ${sp}^{3} d^{2}$ hybrid orbitals.

Here hybridization is ${sp}^{3} d^{2}$ .

The shape is octahedral.

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