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Q.

Of the given anions, the strongest Bronsted base is

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a

ClO-

b

ClO3-

c

ClO2-

d

ClO4-

answer is A.

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Detailed Solution

The acidic strength of chlorate acids are as follows:

HClO4HClO3HClO2HClO 

The corresponding strength of their conjugate bases are        ClO4-,ClO3-,ClO2-,ClO- 

When the acid is strong, the corresponding conjugate base will be weak because the ensuing conjugate base becomes more stable and does not react when acids give up their protons.

Following is the order of the conjugate bases' basic strengths:

ClO4- ClO3- ClO2- ClO-

The strongest base will be ClO-.

Hence, the correct option is option (A) ClO-.

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