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Q.

Of the species NO,NO+,NO2+ and NO-, the one with minimum bond strength is

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a

NO

b

NO2+

c

NO+

d

NO-

answer is D.

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Detailed Solution

BO=NbNa2

Energy order of MO s

σ1sσ1sσ2sσ2sπ2px=π2pyσ2pzπ2px=π2py

Speciesσ1sσ1s*σ2sσ2s*π2px=π2pyσ2pzπ2px*=π2py*B.O =NBMO-NABMO2
NO2222           221              0B.O =10-52=2.5
NO+22222           220              0B.O =10-42=3
NO+222222           210              0B.O =9-42=2.5
NO-22222           221               1B.O =10-62=2

 We know, Bond length 1BO (Bond order) 1 Bond strength 

So, the order of bond strength : NO+>NO=NO2+>NO

So, NO- has minimum bond strength.

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