Q.

On adding Zinc granules to freshly prepared Ferrous sulphate solution, a student observes that

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a

No coating is formed

b

A black coating is formed

c

a greyish coating is formed

d

A dull brown coating is formed

answer is A.

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Detailed Solution

Zinc displaces Fe from FeSO4 as it is more reactive than iron.

1. Chemical Reaction

When zinc granules are added to a freshly prepared ferrous sulfate (FeSO4) solution, a displacement reaction occurs:

Zn (s) + FeSO4 (aq) → ZnSO4 (aq) + Fe (s)

2. Observations

  • Color Change: The light green color of the ferrous sulfate solution fades as zinc sulfate, which is colorless, forms in the solution.
  • Metal Deposition: A grayish-black deposit of iron appears on the surface of the zinc granules.
  • Effervescence (Optional): If impurities are present in the zinc or trace amounts of acid exist in the solution, slight effervescence may occur due to the release of hydrogen gas.
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