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Q.

On reaction with sodium, 1 mol of a compound X gives 1 mol of H2. Which one of the following compounds might be X?

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a

CH3COOCH2CH3

b

CH2CH2CH=CH2

c

CH3CH2CH2OH

d

CH2OHCH2CH2CH2OH

answer is D.

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Detailed Solution

Since 1 mole of compound X reacts with Na  to evolve 1 mole of H2 gas, therefore the compound should have 2 active hydrogen atoms per mole which is possible only in option d.

CH2OHCH2CH2CH2OH+2Na

NaOCH2CH2CH2ONa+H

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