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Q.

On adding excess of chlorine water to potassium iodide solution containing little carbon tetra chloride gives first violet colour to carbon tetrachloride and then violet colour is discharged. The change in the oxidation state of iodine from initial to final compound is

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answer is 6.

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Detailed Solution

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Oxidation State Change of Iodine in Reaction with Chlorine Water

When excess chlorine water is added to potassium iodide solution containing a little carbon tetrachloride, the solution first shows a violet color (due to iodine dissolved in CCl4) and then the violet color disappears. This corresponds to the oxidation of iodide ions to iodic acid.

Redox reactions involved:

Cl2 + H2O → 2HCl + [O]

I2 + 5[O] → I2O5

I2O5 + H2O → 2HIO3

Overall: I2 + 5Cl2 + 6H2O → 2HIO3 + 10HCl

SpeciesOxidation State of Iodine
Iodide ion (I⁻) in KI-1
Elemental iodine (I2)0
Iodic acid (HIO3)+5

Conclusion: The oxidation state of iodine changes from -1 initially to +5 in the final iodic acid.

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