Q.

On adding AgNO3 solution to KI solution, a negatively charged colloidal sol will be formed in which of the following conditions?

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a

100ML of 0.1MAgNO3+100 mL of 0.15MKI

b

100ML of 0.1MAgNO+ 3 50 mL of 0.2MKI

c

100ML of 0.1MAgNO+300 mL of 0.1MKI

d

100ML of 0.2MAgNO3+100 mL of 0.1MKI

answer is B.

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Detailed Solution

 When AgNO3 completely precipitates as Agl and additional KI is absorbed on Agl , a negatively charged colloidal sol is created. 

Ag++I-Agl AgI+I-[Ag1]- Thus, Ag+<I-

Hence the correct option is (B).

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