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Q.

On adding KI to benzenediazonium chloride, the product obtained is

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a

benzene

b

1-4-diiodobenzene

c

iodobenzene

d

1,3,5-triiodobenzene

answer is C.

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Detailed Solution

Treating with KI produces iodobenzene.  When benzene diazonium chloride reacts with potassium iodide, iodobenzene is obtained. Diazonium group is replaced with −I.

C6H5N2+Cl+KIΔC6H5I+N2+KCl

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