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Q.

On heating aniline with ${CS}_{2}$ in the presence of ${HgCl}_{2}$ the product is

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a

Phenyl isocyanide

b

Phenyl isothiocyanate

c

p-amino benzene sulphonic acid

d

Phenyl cyanide

answer is C.

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Detailed Solution

Aniline is a primary amine and when heated with ${CS}_{2}$ forms a dithiocarbonic acid compound. This compound when further treated with ${HgCl}_{2}$ forms phenyl isothiocyanate along with $HgS$ and 2 moles of hydrochloric acid as by products. Hence, the final product formed from the given reaction scheme is phenyl isothiocyanate.

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