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Q.

On heating K4Fe(CN)6 with conc. H2SO4 gives the gas

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a

SO2

b

CO2

c

NO2

d

CO

answer is C.

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Detailed Solution

Potassium hexacyanoferrate(II) react with sulfuric acid and water to produce potassium sulfate, iron(II) sulfate, ammonium sulfate and carbon monoxide.

K4​Fe(CN)6​ + 6H2​SO4​ + 6H2​O → 2K 2​SO4​ + FeSO4​ + 3(NH4​)2​SO4​ + 6CO

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On heating K4Fe(CN)6 with conc. H2SO4 gives the gas