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Q.

On heating, lead (II) nitrate gives a brown gas (A). The (A) on cooling changes to a colourless solid/liquid (B).on heating with NO changes to a blue solid (C). oxidation number of nitrogen in solid (C) is

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a

+5

b

+3

c

+4

d

+2

answer is B.

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Detailed Solution

PbNO32ΔPbO+2NO2   Brown gas +12O2(g)                                     (A)

2NO2(g) Cooling N2O4(B)

N2O4+2NO      2 N2O3 Blue solid (C)

O .S. of nitrogen in N2O3 is +3

N2O3 : 2x+3(2)=0x=+3.

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On heating, lead (II) nitrate gives a brown gas (A). The (A) on cooling changes to a colourless solid/liquid (B).on heating with NO changes to a blue solid (C). oxidation number of nitrogen in solid (C) is