Q.

On hydrolysis of a "compound", two compounds are obtained. One of which on treatment with sodium nitrite and hydrochloric acid gives a product which does not respond to iodoform test. The second one reduces Tollen's reagent and Fehling's solution. The "compound" is

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a

CH3CH2CH2NC

b

CH3CH2CH2CN

c

CH3CH2CH2ON=O

d

CH3CH2CH2CONCH32

answer is A.

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Detailed Solution

CH3CH2CH2NC+2H2OCH3CH2CH2NH2+HCOOH                                                       I                     II   II (HCOOH)  reduces Tollen's reagent and Fehling's solution I does not respond to iodoform test

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