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On mixing 35 mL of acetone with 45 mL of chloroform, the total volume of the solution is

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less than 80 mL

equal to 80 mL

unpredictable

more than 80 mL

answer is A.

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Detailed Solution

A mixture of chloroform $(C H C l_{3})$ and acetone ${(C H_{3})}_{2} C O$ slows negative deviations from Raoult’s law due to formation of hydrogen bonding between the two molecules. Hence, a slight decrease in volume takes place.

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