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Q.

On passing 0.5 mole of electrons through CuSO4 and Hg2(NO3)2 solutions in series using inert electrodes:

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a

0.5 mole of Cu deposited

b

0.5 mole of Hg deposited

c

0.125 mole of O2 produced in each solution

d

0.5 mole of O2 produced in each solution

answer is B, C.

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Detailed Solution

 Cathode : Cu(aq)2++2eCu(s)
1 mole of Cu deposited  2 mole of electrons
Hg2(aq)2++2e2Hg(l)
1 mole of Hg, deposited  1 mole of electrons
Anode (each cell) :
2H2O(1)4H(aq)++O2(g)+4e
1 mole of O 4 mole of electrons

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On passing 0.5 mole of electrons through CuSO4 and Hg2(NO3)2 solutions in series using inert electrodes: