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Q.

On reacting excess of CoCl3. xNH3 with one mole of AgNO3, one mole of AgCl is formed. What is the value of 'x'? (Assume that the coordination number is 6).

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a

1

b

4

c

3

d

2

answer is B.

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Detailed Solution

CoCl3. XNH3 gives 1 mole of AgCl. So one Cl- ion is outside the complex. So 2 Cl- and 4NH3 satisfy coordination number 6. 

From the given data the possible complex is

CoNH34Cl2Cl

So x is 4

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