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Q.

On the basis of above Ellingham diagram, select the incorrect statement.

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a

Carbon can be used to reduce any metal oxide at a high temperature.

b

ΔS(C,CO)<ΔSC,CO2

c

Upto 710oC, formation of CO2 is more favourable energetically but above 710oc, the formation of CO is preferred.

d

Carbon reduces many oxides at elevated temperature because ΔfGis temperature line with negative slope.

answer is C.

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Detailed Solution

(i) C(s)+12O2(g)CO(g) (ii) C(s)+O2(g)CO2(g)
S for reaction (i) is positive, since the number of moles of gases increases.
S for reaction (ii) is zero, since there is no change in the number of moles of gases.

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