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Q.

On the basis of the following observations made with aqueous solutions.

FormulaMoles of AgCl precipitated per mole of the compounds with excess AgNO3
I. PdCl2.4NH32
II. NiCl2.6H2O2
III. PtCl4.2HCl0
IV. CoCl3.4NH31
V. PtCl2.2NH30

The secondary valencies of I and IV is

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a

4 and 5 respectively

b

4 and 6 respectively

c

 2 and 4 respectively

d

 6 and 4 respectively

answer is B.

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Detailed Solution

Pd  Cl2.4NH3PdNH34Cl2

 20 valency = 4

CoCl3.4NH3CoNH34Cl2Cl

  20 valency = 6

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