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Q.

On the basis of the information available from the reaction 43Al+O223Al2O3;ΔG=827kJ/mol. The minimum emf required to carry the electrolysis of Al2O3  is

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a

8.56V

b

4.28V

c

6.42V

d

2.14V

answer is B.

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Detailed Solution

43Al+O223Al2O3
 43(0)23(+3) 02 n=2 ΔG=nFEcell 827×103=2×96500×Ecell=4.28V

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