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On the basis of VSEPR theory, what geometry is predicted for the central sulphur atom in SOCl2?

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By Expert Faculty of Sri Chaitanya
a
Tetrahedral
b
T-shaped
c
Trigonal planar
d
Trigonal pyramidal

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detailed solution

Correct option is D

SOCl2 is shaped like a pyramid. The core atom of sulphur possesses six electrons in its valence orbit, which explains why. Out of the remaining four electrons, two are in the S orbit and two are in the P orbit. The triangular pyramidal sulphate atom at its centre is present.

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