Q.

On treatment of 100mL of 0.1M Solution of CoCl3.6H2O with excess of AgNO3, 1.2×1022 ions are precipitated. The complex is

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a

Co(H2O)3Cl3.3H2O

b

Co(H2O)6Cl3

c

Co(H2O)4Cl2Cl.H2O

d

Co(H2O)5ClCl2.H2O

answer is D.

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Detailed Solution

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0.1=n×1000100n=0.01moles

no.ofmoles=givenno.ofionsAvagadomno.

=1.2×10226.023×1023

= 0.02 mol

Hence two chloride ions can be precipitated

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