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Q.

One Faraday of electricity is passed through molten Al2O3, aqueous solution of CuSO4 and molten NaCl taken in three different electrolytic cells connected in series. The mole ratio of Al, Cu and Na deposited at the respective cathode

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a

6 : 3 : 2

b

2 : 3 : 6

c

6 : 2 : 3

d

1 : 2 : 3

answer is A.

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Detailed Solution

The charge carried by 1 mole of electron is one faraday. Thus for a reaction  Mn++neM

nF = 1 mole of M

Al3+3F1F+3eAl1mol1/3mol

Cu2+2F1F+2eCu1mol1/2mol

Na+1FNa1mol

The mole ratio of Al, Cu and Na deposited the respective cathode is 13:12:1   or   2:3:6

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One Faraday of electricity is passed through molten Al2O3, aqueous solution of CuSO4 and molten NaCl taken in three different electrolytic cells connected in series. The mole ratio of Al, Cu and Na deposited at the respective cathode