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Q.

One gram of Na3AsO4 is boiled with excess of solid KI in presence of strong HCl. The iodine evolved is absorbed in Kl solution and titrated against 0.2 N hypo solution. Assuming the reaction to be:

AsO43+2H++2IAsO33+H2O+I2

Calculate the volume of hypo consumed. [Atomic weight of As = 75]

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a

24.7 mL

b

30.3 mL

c

38.4 mL

d

48.1 mL

answer is A.

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Detailed Solution

Here, in the reaction

AsO43+2H++2IAsO33+H2O+I2

In this reaction n factor is 2.

The volume which is consumed by the hypo;

12082=0.2×V1000

So, volume V=48.1 mL

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One gram of Na3AsO4 is boiled with excess of solid KI in presence of strong HCl. The iodine evolved is absorbed in Kl solution and titrated against 0.2 N hypo solution. Assuming the reaction to be:AsO43−+2H++2I−⟶AsO33−+H2O+I2Calculate the volume of hypo consumed. [Atomic weight of As = 75]