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Q.

One mole of 1,2- dibromopropane on treatment with X moles of  NaNH2  followed by treatment with ethyl bromide gave a Pent-2-yne. The value of X is

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answer is 3.

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Detailed Solution

NaNH2 is a strong base. It mediates formation of alkyne via elimination reaction. Treatment of 1,2-dibromopropane for the formation of pentyne requires 3 moles of NaNH2. In which 2 moles form a propyne by two consecutive eliminations of HBr. The third mole of NaNH2 produces propyne carbanion which reacts with C2H5Br and forms Pentyne.

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