Q.

One mole of a compound AB reacts with 1 mole of a compound CD according to the equation

AB+CD  AD + CB.

When equilibrium had been established it was found that 34 mole each of reactant AB and CD had been converted  to AD and CB. There is no change in volume. The equilibrium constant for the reaction is

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a

169

b

916

c

9

d

19

answer is D.

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Detailed Solution

                                    AB + CD   AD  +  CD

mole at t = 0 :               1          1           0          0

at equilibrium:    1-34    1-34  34   34

                             0.25         0.25         0.75      0.75  

KC=0.75 × 0.750.25 × 0.25=0.56250.0625=9

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