Q.

One mole of an ideal diatomic gas Cv=5cal was transformed from initial 25°C and 1 L to the state when temperature is 100C and volume 10 L. The entropy change of the process can be expressed as : (R=2cal/mol/K)

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a

5ln373298+2ln10

b

3ln298373+2ln10

c

7ln373298+2ln110

d

5ln373298+2ln110

answer is B.

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Detailed Solution

Changes to the entropy formula in general

ΔSsyn=nCvlnT2T1+nRlnV2V1

given value 

T1=25C=298k

T2=100C=373K

Cv=5Cal

R=2Cal/molK

V1=1LV2=10L

ΔS=5ln373298+2ln101

=5ln373298+2ln10

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