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Q.

One mole of an ideal gas requires 207 J heat to raise it’s temperature by 10 K when heated at constant pressure. If the same gas is heated at constant volume the heat required to raise the temperature by 10 K for the same gas, will be : (given R=8.3 J/mol/K)

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a

124 J

b

198.7 J

c

29 J

d

215.3 J

answer is B.

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Detailed Solution

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amount of heat required to raise the temperature of gas at constant pressure is Qp=nCpT

given Qp=207Joule;number of mole n=1;change in temperature T=10K

     substitute the given values in above equation of Qp  207=1×Cp×10.........(1)amount of heat required to raise the temperature of gas at constant volume is Qv=nCvTgiven n=1;T=10K, substitute in Qv  Qv=1×Cv×10 ........(2)  subtract, eqn(1)-eqn(2),  (207-Qv)=10(CpCv) 207-Qv=10×8.3=83 Qv=207-83 Qv=124 J

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