Q.

One mole of anhydrous MgCl2 dissolves in water and liberates 25cal/mol of heat.Hhydration of MgCl2 = -30 cal/mol . Heat of dissolution of MgCl2 .H2O is


 

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a

-55cal/mol

b

+5cal/mol

c

-5cal/mol

d

55cal/mol

answer is A.

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Detailed Solution

MgCl2(S )+H2O(l)MgCl2(aq)+25Cal

HHydration of MgCl2=-30Cal

so heat of dissolution of MgCl2.H2O is =+5 Cal/mol

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