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Q.

One mole of diatomic gas is being heated in a closed tank from 300K up to 1000 K. During the process part of the molecules dissociate. At 1000 K the energy of the diatomic molecules are only half of that of the whole gas. By what factor has the gas pressure increased (Pfinal/Pinitial)? (The oscillation of the molecules are not to be taken in account).

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a

16033

b

1611

c

32

d

23

answer is A.

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Detailed Solution

Let n moles of diatomic gas dissociate into monoatomic. Then mono 2n moles and dia 1 – n moles n=511
PfinalPinitial=16033
 

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