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Q.

One mole of  FeC2O4 is separately oxidized by KMnO4 and K2Cr2O7 in acid medium into Fe3+ ions and CO2 molecules. Which statements are true 

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a

Equivalent weight of FeC2O4 is 1/3rd  of its formula weight

b

FeC2O4 undergoes disproportionation

c

The ratio of number of equivalents of KMnO4 and K2Cr2O7 required is 1:1

d

The mole ratio of KMnO4 and K2Cr2O7 required is 6:5

answer is A, B, C.

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Detailed Solution

In acidic medium, MnO4 + 8H+ + 5e Mn2+ + 4H2O

Cr2O72+ + 14H+ + 6e 2Cr3+ + 7H2O

Fe2+ + C2O42- Fe3+ + 2CO2 + 2e

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