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Q.

One mole of magnesium in the vapour state absorbed 1300kJ of energy. If the first and second ionization energies of Mg are 750 and 1450 kJ /mol respectively, the final composition of mixture is

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a

41%Mg2+   and  59%Mg+

b

59%Mg2+  and  41%Mg+

c

62%Mg2+   and  38%Mg+

d

38%Mg2+   and  62%Mg+

answer is B.

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Detailed Solution

IP1=750 , Energy available for  IP2=1300750=550
1450kj will convert  Mg+(g)   to   Mg2+(g) = 1 mole
550kj will convert Mg+(g)   to   Mg2+(g)  = 0.38 mole

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One mole of magnesium in the vapour state absorbed 1300kJ of energy. If the first and second ionization energies of Mg are 750 and 1450 kJ /mol respectively, the final composition of mixture is