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Q.

One mole of O2 gas having a volume equal to 22.4 litres at 00C and 1 atmospheric pressure in compressed isothermally so that its volume reduces to 11.2 litres. The work done in this process is

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a

1672.5J

b

1728J

c

–1728J

d

–1572.5J

answer is D.

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Detailed Solution

V1=22.4 litres ;V2=11.2 litres R=1 atmospheric pressure T=273+0=273k; n=1 mole W=2.303nRTlogV2V1=1×8.314×273×2.3026log1011.222.4=273×2.3026×8.314×(0.3010)=8.314×2.3026×273×(0.3010)=1573.101572.5J

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