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Q.

One mole of sulphur monochloride  S2Cl2 loses six moles of electrons to form a compound of sulphur. Oxidation state of sulphur in the product is (Assume chlorine atoms doesn’t show any change in oxidation state and both sulphur atoms appear in the product)

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a

+6

b

+3

c

+4

d

+2

answer is A.

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Detailed Solution

S+12Cl2

Total oxidation number of sulphur/mole of  S2Cl2 = +2
1 mole of S2Cl2  loses ‘6’ moles of electrons
 Total increase in oxidation number = 6
Sum of oxidation numbers of two sulphur atoms in one mole of product = 2+6 = +8
2x = +8
         x = +4
Oxidation number of sulphur in the product = +4

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